Ok, first, I assume you mean each flash meters at f/8, rather than the two together.
Second, we have to know if the flash duration is t.5 measurement or t.1 measurement, for each light. The flash duration is typically a t.5 time, unless otherwise noted. This means the time that it takes for 50% of the flash to discharge. The time it takes 90% of the light to discharge is the t.1 time, and is typically 3x as long for voltage controlled or capacitor switching lights. So your t.1 time for the respective lights is roughly 1/3000 and 1/100 of a second. Some cases, when IGBT technology is used the really short durations are t.1 times (in the case of Einstein, for example, or speedlites).
So, assuming these are t.5 times, a x-sync shutter speed of 1/250 will capture all of light 1 but miss a fairly significant portion of light 2 (1/3 to 2/3 of a stop). A slower shutter speed will capture the same amount of light 1, but stay open longer to capture more of light 2, which means light 2 *could* meter higher at a slower shutter speed.
If these are t.1 times, then a 1/250s shutter speed would probably capture both in their entirety (or nearly enough) that both are contributing equally and neither would benefit from a longer exposure.
Lastly, it is important to note, if you are metering in the 1/10 stop scale, f/8.0'0 is essentially one stop less than f/8.0'9, as f/8.0'9 is just 1/10 of a stop below f/11. So when metering, pay attention to the numbers after the apostrophe (or they may just be smaller numbers, depending on the meter). Also, if metering in 1/3 stops, there could be a 1/3 stop difference, but the meter would not show it.
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