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Very well could be the remotes overall quality. Also, you say "usually" you have your camera at those settings. What do you have set when not at those settings? if you exceed the x-sync on a Pentax, my understanding is the flash will not fire (unless it is a dedicated flash). Have you tried new batteries on the transmitter? Is it radio or IR? If IR, then it will suffer the same as any other line of sight triggering, in that it works great, as long as the slave eye can see it (if you can't see the slave eye, don't bet it can see the optical signal).
If you still have (presumably) black frames from the misfires, what does the EXIF data say?
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